Surface plasmon resonance of gold nanoparticle aggregates induced by halide ions

Publication date: 15 Ott 2023

JournalSource: LEGACY
Authors: Mario Scuderi

The localized surface plasmon resonance (LSPR) of metal nanoparticles is strongly dependent on geometrical and environmental factors, as well as the nanoparticle aggregation phenomena, which are exploited in a range of applications. In this work we investigate the LSPR of gold nanoparticles, produced by laser ablation in liquid (LAL), and their agglomeration induced by halides after LAL. We study the aggregation process under a range of factors like bromide concentration, temperature, and different halides. By absorption spectroscopy and electron microscopy we show that increasing bromide concentration leads to longer and more complex aggregates, with consequent red-shift and broadening of the LSPR. Simulations, in agreement with experiments, show that a red-shift of the LSPR is expected as AuNP linear chains become longer and validate this trend for different particle size and gap between …

Publisher
Elsevier
Origin
Materials Chemistry and Physics
Legacy ID
66307646434915fbf1359bf52eb9eadb
Biblio references
Volume: 308 Pages: 128245