Solid-state electro-active photonic crystals based on Tantalum-doped Titanium Dioxide multilayers

Publication date: 2 Nov 2025

JournalSource: OPENALEXOpenAlex type: articleOpen Access
Authors: Cristina Mancarella, Liliana Moscardi, Giancarlo Terraneo, Alessio Lamperti, Marzia Iarossi, Francesco De Angelis, Francesco Scotognella, Andrea Li Bassi

ABSTRACT Photonic crystals can manipulate light by impeding transmission through photonic band gaps (PBGs), unlocking vivid structural colors and beating conventional spectrally-selective pigments. Nowadays, research is targeting at active and electrically-driven devices, moving beyond stacks of inert dielectrics. Plasmonic Transparent Conductive Oxides (TCOs) become appealing owned to their adjustable charge carrier density upon external stimuli (electrical biases), that enable electro-active control even in complex photonic architectures. Here, pioneer compact/porous one-dimensional PC multilayers, completely solid and entirely based on the novel and earth-abundant Tantalum-doped Titanium Dioxide TCO (Ta:TiO 2 ), have been developed with pulsed laser deposition through an original one-step method, by mastering the oxygen supply at deposition. Engineered doping and geometry enable tunable PBGs in the visible range. Electro-doping achieves PBG blue-shifts of 11-16 nm under low bias (≤7 V) without liquid electrolytes. These findings unveil the potential of actively-tunable Ta:TiO 2 PCs to foster technological advancements in electro-optic switches, biosensors and anticounterfeit devices.

Origin
Optical Materials
Volume
169
Pages
117646
Cited by
0